Product ID:CLEANING FLUID BLEND
MSDS Date:01/05/1996
FSC:6850
NIIN:00N075571
MSDS Number: CDWWF

ASHLAND CHEMICAL CO

COLUMBUS, OH 43216
US

Emergency Phone: 800-274-5263

Info Phone: 614-790-3333

Cage: 34897

ASHLAND CHEMICAL CO

2219 COLUMBUS, OH 43216-2219 US

Telephone: 614-790-3333/800-274-5263

Cage: 34897

CYCLOHEXANE (SARA 313) (CERCLA)

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: 67%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ISOPROPYL ALCOHOL; (ISOPROPANOL) (SARA 313)

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: 33%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM;500 STEL

BENZENE (SARA 313) (CERCLA)

CAS: 71-43-2

RTECS: CY1400000

OSHA PEL SEE 1910.1028

ACGIH TLV: 10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

MILD, REVERSIBLE

RTECS: 9999999ZZ

IN LAB ANIMAL STUDIES. HARM TO FETUS OCCURS ONLY AT

RTECS: 9999999ZZ

BENZENE IS KNOWN TO STATE OF CALIFORNIA TO CAUSE

RTECS: 9999999ZZ

COMPLETED. STOP SPILL AT SOURCE. PVNT FROM

RTECS: 9999999ZZ

PVNT FROM SPREADING. IF RUN-OFF OCCURS, NOTIFY AUTHS

RTECS: 9999999ZZ

CNTNRS FOR RECOVERY. ABSORB UNRECOVERABLE PROD.

RTECS: 9999999ZZ

DISP. PVNT RUN-OFF TO SEWERS, STREAMS/OTHER BODIES OF

RTECS: 9999999ZZ

REQUIRED, THAT A SPILL HAS OCCURRED.

RTECS: 9999999ZZ

INGRESS OF AIR INTO VACUUM EQUIP, MAY RSLT IN

RTECS: 9999999ZZ

PUBLISHED "AUTOIGNIT"/"IGNIT" TEMPS VALUES CANNOT BE

RTECS: 9999999ZZ

W/OUT ANALYSIS OF ACTUAL PROCESS CNDTNS. ANY USE OF

RTECS: 9999999ZZ

EVALUATED TO ESTABLISH & MAINTAIN SAFE OPERATING

RTECS: 9999999ZZ

DOWN. CONT MD, MED FACILITY/POIS CTL CTR FOR

RTECS: 9999999ZZ

MOVE

RTECS: 9999999ZZ

PERSIST, SEEK MED ATTN. IF BRTHG IS DFCLT, ADMIN

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE:EYE:IRRIT; STINGING, TEARING,
REDNESS & SWELL. SKIN:MILD IRRIT; REDNESS, BURNING, DRYING,
CRACKING & BURNS. ABSORPTION IS POSS. INGEST:TOX IS LOW. LG AMTS
MAY BE HARMFUL. MATL CAN ENTER LUNGS DU RING SWALLOWING/VOMIT &
CAUSE LUNG INFLAMM &/OR DMG. INHAL:TOX IS LOW. LG AMTS MAY BE
HARMFUL. SIGNS & (EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE:IARC MONO, SUPP, VOL 7, PG 120,
1987:GRP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994:KNOWN TO BE CARCIN.
OSHA(SUPDAT)
Effects of Overexposure:HLTH HAZ:SYMPS MAY INCL:GI IRRIT (NAUS, VOMIT,
DIARR); IRRIT (NOSE, THROAT, RESP TRACT); CNS DEPRESS (DIZZ, DROW,
WEAK, FATG, NAUS, HDCH, UNCON); LOW BLOOD PRESS; MILD, REVERSIBLE
LIVER EFTS; EFTS ON HEART RATE; RESP DEPRESS; IMPAIRED COORD;
CONFUSN; PULM EDEMA (SWELL & COLLECTION OF FLUID IN LUNGS); KIDNEY
(ING 4)
Medical Cond Aggravated by Exposure:PREEXISTING DISORDERS OF THE
FOLLOWING ORGANS (OR ORGAN SYSTEMS) MAY BE AGGRAVATED BY EXPOSURE
TO THIS MATERIAL: SKIN, LIVER.

First Aid:EYES:IMMED MOVE INDIVIDUAL AWAY FROM EXPOS & INTO FRESH AIR.
FLUSH GENTLY W/WATER FOR AT LST 15 MINS WHILE HOLDING EYELIDS
APART; SEEK IMMED MED ATTN. SKIN:REMOVE CONTAM CLTHG. WASH EXPOS
AREA W/SOAP & WATER. IF SYMPS PERSISTS, SEEK MED ATTN. LAUNDER
CLTHG BEFORE REUSE. INGEST:SEEK MED ATTN. IF INDIVIDUAL IS
DROWSY/UNCON, DO NOT GIVE ANYTHING BY MOUTH; PLACE INDIVIDUAL ON
LEFT SIDE W/HEAD (ING 16)

Flash Point Method:TCC
Flash Point:<-1F,<-18C
Lower Limits:1.3%
Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . REFER TO PERSONAL PROTECTIVE EQUIPMENT SECTION OF THIS
MSDS.
Unusual Fire/Explosion Hazard:MATL IS HIGHLY VOLAT & READILY GIVES OFF
VAPS WHICH MAY TRAVEL ALONG GROUND/BY MOVED BY VENT & IGNITED BY
PILOT LIGHTS, OTHER FLAMES, SPKS, HEATERS, (SUPP DATA)

Spill Release Procedures:SM SPILL:ABSORB LIQ ON VERMICULITE, FLOOR
ABSORB/OTHER ABSORB MATL. LG SPILL:ELIM ALL IGNIT SOURCES (FLARES,
FLAMES INCL PILOT LIGHTS, ELEC SPKS). PERS NOT WEARING PROT EQUIP
SHOULD BE EXCLUDED FROM A REA OF SPILL UNTIL CLEAN-UP IS HAS
BEEN(ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CNTNRS OF THIS MATL MAY BE HAZ WHEN
EMPTIED. SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES (VAP, LIQ &/OR
SOLID), ALL HAZ PRECS IN MSDS MUST BE OBSERVED.
Other Precautions:ALL 5 GAL PAILS & LGR METAL CNTNRS INCL TANK CARS &
TANK TRUCKS SHOULD BE GROUNDED &/OR BONDED WHEN MATL IS
TRANSFERRED. WARNING! SUDDEN RELS OF HOT ORG CHEM VAPS/MISTS FROM
PROCESS EQUIP OPERATING AT ELEVATED TEMP & PRESS/SUDDEN (ING 12)

Respiratory Protection:IF WORKPLACE EXPOS LIMS OF PROD/ANY ING IS
EXCEEDED, NIOSH APPRVD AIR SUPPLIED RESP IS ADVISED IN ABSENCE OF
PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT OTHER NIOSH APPRVD RESPS
(NEG PRESS TYPE) UNDER S PECIFIED CNDTNS (SEE INDUS HYGIENIST).
Ventilation:PROVIDE SUFFICIENT MECH (GEN &/OR LOC EXHST) VENT.
ENGINEERING/ADMIN CONTROLS SHOULD BE IMPLEMENTED TO REDUCE
EXPOSURE.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . WEAR IMPERVIOUS CLOTHING & BOOTS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN:REG:29 CFR 1910.1028. HUMAN:MYELOID LEUKEMIA. HODGKINS
DISEASE, LYMPHOMA. EXPLO HAZ:SMOKING, ELEC MOTORS, STATIC
DISCHARGE/OTHER IGNIT SOURCE AT LOCATIONS DIST FROM MATL HNDLG
POINT. NEVER USE WELDING/CUTTING TORCH ON/NEARDRUM (EVEN EMPTY)
BECAUSE PROD (EVEN JUST RESIDUE) CAN IGNITED EXPLOSIVELY.

Boiling Pt:B.P. Text:179F,82C
Vapor Pres:78 @ 68F
Vapor Density:>1
Spec Gravity:0.787
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Appearance and Odor:LIQUID; HOMOGENEOUS SOLUTION.

Stability Indicator/Materials to Avoid:YES
AVOID CONT W/ACETALDEHYDE, ACIDS, CHLORINE, ETHYLENE OXIDE ISOCYANATES,
STRONG OXIDIZING AGENTS & ALUMINUM.
Stability Condition to Avoid:DO NOT USE W/ALUMINUM EQUIPMENT AT
TEMPERATURES >120F.
Hazardous Decomposition Products:MAY FORM: CARBON DIOXIDE & CARBON
MONOXIDE, VARIOUS HYDROCARBONS.

Waste Disposal Methods:DISPOSE OF I/A/W ALL APPLICABLE LOCAL, STATE &
FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.